Enzyme Technology
Summary and Bibliography of Chapter 7
- Reaction
equilibria can be shifted by use of biphasic systems. This may be utilised by
enzyme technologists so long as their enzymes are stable within such systems.
- LogP is the best measure of the polarity of a
solution for use in enzymic reactions.
- Kinetic control may be preferred
to thermodynamic control in some enzymic syntheses.
References and Bibliography
- Carrea, G.,
Riva, S., Bovara, R. & Pasta, P. (1988). Enzymatic oxidoreduction of
steroids in two-phase systems: effects of organic solvents on enzyme kinetics
and evaluation of the performance of different reactors. Enzyme and Microbial
Technology, 10, 333-340.
- Deetz,
J.S. & Rozzell, J.D. (1988). Enzyme-catalysed reactions in non-aqueous
media. Trends in Biotechnology, 6, 15-19.
- Klibanov, A.M. (1986). Enzymes that work in organic solvents.
CHEMTECH, 16, 354-359.
- Laane, C., Boeren, S., Vos,
K. & Veeger, C. (1987). Rules for optimization of biocatalysts in organic
solvents. Biotechnology and Bioengineering,
30, 81-87.
- Lilly, M.D. (1982). Two-liquid-phase biocatalytic
reactions. Journal of Chemical Technology and Biotechnology,
32, 162-169.
- Luisi, P.L. & Laane, C. (1986). Solubilization
of enzymes in apolar solvents via reverse micelles. Trends in Biotechnology, 4,
153-160.
- Martinek, K. & Semenov,
A.N. (1981). Enzymic synthesis in biphasic aqueous-organic systems. 2. Shift in
ionic equilibria. Biochimica et Biophysica Acta,
658ES70, 90-101.
- Martinek, K., Semenov, A.N. & Berezin, I.V.
(1981). Enzymic synthesis in biphasic aqueous-organic systems. 1. Chemical
equilibrium shift. Biochimica et Biophysica Acta,
658, 76-89.
- Morihara, K. (1987). Using proteases in peptide
synthesis. Trends in Biotechnology, 5, 164-170.
- Nilsson, K.G.I. (1988). Enzymatic synthesis of
oligosaccharides. Trends in Biotechnology, 6, 256-264.
- Rekker, R.F. & de Kort, H.M. (1979). The
hydrophobic fragmental constant; an extension to a 1000 data point set. European
J. Medicinal Chemistry,
14, 479-488.
- Visuri, K. & Klibanov, A.M. (1987). Enzymic
production of high fructose corn syrup (HFCS). containing 55% fructose in
aqueous ethanol. Biotechnology and Biopengineering, 30, 917-920.
- Zaks, A., Empie, M. & Gross, A.
(1988).Potentially commercial enzymatic processes for the fine and specialty
chemical industries. Trends in Biotechnology, 6, 272-275.
- Zaks, A. & Klibanov, A.M. (1984). Enzymic catalysis in organic media
at 100°C. Science, 224, 1249-1251.
- Zaks, A. & Klibanov, A.M. (1985). Enzyme-catalyzed processess in
organic solvents. Proceedings of the National Academy of Sciences, 82,
3192-3196.
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